Mechanical Property Evaluation and Prediction of Cementing Composites Blended with MK and UFA under High-Temperature Steam Curing

Abstract

In this paper, the influence of the substitution rate of metakaolin (MK) and ultrafine fly ash (UFA) on the hydration degree, the micromechanical properties, the pore size distribution, and the corresponding fractal dimension of composite cement-based material was investigated under high-temperature steam curing. Furthermore, Thermogravimetric, Nanoindentation, and low-field nuclear magnetic resonance tests were used to explore the influencing factors of pore size distribution and its corresponding multi-fractal dimension. Finally, the correlations among the pore size distribution, related fractal dimensions, and compression strength were analyzed. Results indicate that the MK-UFA cement ternary cementation system (TCS) can improve the compressive strength and fluidity of samples and enhance the hydration degree and micromechanical properties of the cementitious system. TCS effectively refines the pore size and increases microporosity. In addition, micropore and its fractal dimension have a stronger correlation with the compressive strength of composite cement-based materials. Furthermore, the micro-fractal dimensions can better reflect the essential characteristics of the composite cementitious system. The higher the degree of hydration of the cementitious system and the nanomechanical properties of the C-(A)-S-H gel, the lower the micro-fractal dimension. Finally, the GM (1,3) prediction model of compressive strength, micro-fractal dimension, and microporosity are established based on the grey relational theory.