Quantitative and Sensitive Mid-Infrared Frequency Modulation Detection of HCN behind Shock Waves

Abstract

Despite its key role for the study and modeling of nitrogen chemistry and NOx formation in combustion processes, HCN has only rarely been detected under high-temperature conditions. Here, we demonstrate quantitative detection of HCN behind incident and reflected shock waves using a novel sensitive single-tone mid-infrared frequency modulation (mid-IR-FM) detection scheme. The temperature-dependent pressure broadening of the P(26) line in the fundamental CH stretch vibration band was investigated in the temperature range 670K≤T≤1460K, yielding a pressure broadening coefficient for argon of 2γAr296K=(0.093±0.007)cm−1atm−1 and a temperature exponent of nAr=0.67±0.07. The sensitivity of the detection scheme was characterized by means of an Allan analysis, showing that HCN detection on the ppm mixing ratio level is possible at typical shock wave conditions. In order to demonstrate the capability of mid-IR-FM spectroscopy for future high-temperature reaction kinetic studies, we also report the first successful measurement of a reactive HCN decay profile induced by its reaction with oxygen atoms.