Use of Deep Eutectic Solvents in Plastic Depolymerization

Author:

Paparella Andrea Nicola12,Perrone Serena1ORCID,Salomone Antonio3ORCID,Messa Francesco1ORCID,Cicco Luciana2,Capriati Vito2ORCID,Perna Filippo Maria2ORCID,Vitale Paola2ORCID

Affiliation:

1. Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali, Università del Salento, Prov.le Lecce-Monteroni, 73100 Lecce, Italy

2. Dipartimento di Farmacia-Scienze del Farmaco, Università degli Studi di Bari “Aldo Moro”, Consorzio CINMPIS, Via E. Orabona 4, 70125 Bari, Italy

3. Dipartimento di Chimica, Università degli Studi di Bari “Aldo Moro”, Consorzio CINMPIS, Via E. Orabona 4, 70125 Bari, Italy

Abstract

Polymeric materials are widely used in every human endeavor (bottles, clothes, containers, toys, tools, etc.) due to their unique properties of chemical and mechanical resistance. They are, however, almost non-biodegradable, and their chemical recycling into monomers is difficult and costly, thereby allowing their accumulation into the environment. This review highlights recent advances in the use of deep eutectic solvents (DESs) as catalysts and/or green solvents in plastics degradation, with the aim of designing greener processes for polymers’ chemical recycling, by reusing their monomers. These greener processes, in combination with other catalytic approaches, are aimed at introducing plastics as feedstock into the synthesis of other materials, according to the circular economy principles.

Funder

Ministero dell’Università e della Ricerca (MUR) through the PRIN project “REPLAY: REconnecting PLAstics life cycle to biogeochemical cycles by sustainable hydrolysis and Yeasts fermentation”

Apulian Regional Project “Green Chemistry and Biocatalysis for the development of new low environmentally friendly methodologies for the transformation of polymer waste”

Horizon SEEDS Project “Carbossilazioni Fotocatalizzate da Perovskiti ad Alogenuro per la Conversione della CO2 in Composti Organici ad Alto Valore Aggiunto (CARBON-ALT)”

Publisher

MDPI AG

Subject

Physical and Theoretical Chemistry,Catalysis,General Environmental Science

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