Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System-Reference-Cited by-同舟云学术

Atom Transfer Radical Addition via Dual Photoredox/Manganese Catalytic System

Published:2023-07-19 Issue:7 Volume:13 Page:1126
ISSN:2073-4344
Container-title:Catalysts
language:en
Short-container-title:Catalysts

Author:

Kostromitin Vladislav S.¹²,Levin Vitalij V.¹,Dilman Alexander D.¹^ORCID

Affiliation:

1. N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991 Moscow, Russia

2. Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, 119991 Moscow, Russia

Abstract

Atom transfer radical addition of bromonitromethane and 1,2-dibromotetrafluoroethane to alkenes is described. The reaction is performed under blue light irradiation using two catalysts: 4CzIPN and manganese (II) bromide. The cyanoarene photocatalyst serves for the redox activation of starting organic bromide, while the manganese salt facilitates the trapping of the alkyl radical with the formation of the carbon–bromine bond.

Funder

Russian Science Foundation

Publisher

MDPI AG

Subject

Physical and Theoretical Chemistry,Catalysis,General Environmental Science

Link

https://www.mdpi.com/2073-4344/13/7/1126/pdf

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