Estimation of Pb Content Using Reflectance Spectroscopy in Farmland Soil near Metal Mines, Central China

Abstract

The contamination of farmlands with hazardous metals from mining puts the safety of agricultural commodities at risk. For remediation, it is crucial to map the spatial distribution of contaminated soil. Typical sampling-based procedures are time-consuming and labor-intensive. The use of visible, near-infrared, and short-wave infrared reflectance (VNIR-SWIR) spectroscopy to detect soil heavy metal pollution is an alternative. With the aim of investigating a methodology of detecting the most sensitive bands using VNIR-SWIR spectra to find lead (Pb) anomalies in agriculture soil near mining activities, the area in Xiaoqinling Mountain, downstream from a series of active gold mines, was selected to test the feasibility of utilizing VNIR-SWIR spectroscopy to map soil Pb. A total of 115 soil samples were collected for laboratory Pb analysis and spectral measurement. Partial least squares regression (PLSR) was adopted to estimate the soil Pb content by building the prediction model, and the model was optimized by finding the optimal number of bands involved. The spatial distribution of Pb concentration was mapped using the ordinary kriging (OK) interpolation method. This study found that five spectral bands (522 nm, 1668 nm, 2207 nm, 2296 nm, and 2345 nm) were sensitive to soil Pb content. The optimized prediction model’s coefficient of determination (R2), residual prediction deviation (RPD), and root mean square error (RMSE) were 0.711, 1.860, and 0.711 ln(mg/kg), respectively. Additionally, the result of OK interpolation was convincing and accurate (R2 = 0.775, RMSE = 0.328 ln(mg/kg)), comparing maps from estimated and ground truth data. This study proves that it is feasible to use VNIR-SWIR spectral data for in situ estimation of the soil Pb content.