Study on Photocatalytic Desulfurization and Denitrification Performance of Cu- and Cr-Modified MWCNT

Abstract

Carbon nanotubes are a promising adsorbent for desulfurization and denitrification. In this paper, Cu- and Cr-doped TiO2 supported by multi-walled carbon nanotubes (MWCNTs/Cu-Cr-TiO2) were synthesized by the sol-gel method. Characterizations of the samples were performed by TEM, XPS, XRD, DRS, and BET. The experiments of simultaneous desulfurization and denitrification were conducted in a fixed-bed reactor. The results showed that the adsorbent with a Cu to Cr molar ratio of 3 displays excellent adsorption property. The SO2 and NO adsorption capacity of MWCNTs/Cu-Cr-TiO2 (Cu/Cr = 3) were 36.83 and 12.34 mg/g under the optimal experimental operating parameters (SO2 content: 1575 mg/m3, NO content 736 mg/m3, O2 content 8%, H2O content 5%, and space velocity 1003 h−1). The adsorption capacity of MWCNTs/Cu-Cr-TiO2 was significantly better than that of the adsorbent doped with Cu or Cr alone (MWCNTs/Cu-TiO2 and MWCNTs/Cr-TiO2). Compared with single metal doping, bimetallic multivalent states accelerate the electron migration and separation from holes, which increase the number of oxygen vacancies and enhance the adsorption of SO2 and NO. The kinetic models and the reaction mechanism of the desulfurization and denitrification were also analyzed in this work.