Efficient Removal of Ammonia Nitrogen by an Electrochemical Process for Spent Caustic Wastewater Treatment

Abstract

Spent caustic wastewater produced in a soda plant has a high concentration of ammonia nitrogen (NH4+-N). As excessive NH4+-N discharging into water bodies would cause eutrophication as well as destruction to the ecology balance, developing an efficient technology for NH4+-N removal from the spent caustic wastewater is imperative in the current society. In this study, an electrochemical process with graphene electrodes was designed for the NH4+-N removal in the spent caustic wastewater. The removal efficiency of the NH4+-N during the electrochemical process could reach 98.7% at 4 A in a short treatment time (within 120 s) with an acceptable energy consumption (6.1 kWh/m3-order). NO3− and NO2− were not detected during the electrochemical process. An insignificant amount of NH2Cl, NHCl2, and NCl3 produced in the treatment suggested that little of the NH4+-N reacted with chlorine, that is, chlorination played a negligible role in the NH4+-N removal. By electron equilibrium and nitrogen conversion analysis, we think that NH4+-N was primarily converted to NH2(ads) on the surface of a graphene electrode by one-electron transfer during the direct oxidation of the electrochemical process. Due to the high calcium ion (Ca2+) in the spent caustic wastewater, the electrode scale significantly increased to 1.4 g after treatment of 240 s at 4 A. By X-ray diffraction (XRD) analysis, the composition of the electrode scale is portlandite Ca(OH)2. Although the electrode scale was obvious during the electrochemical treatment, it could be alleviated by alternating the electrode polarity. As a result, the life and efficiency of the graphene electrode for NH4+-N removal could remain stable for a long time. These results suggest that the electrochemical process with a graphene electrode may provide a competitive technology for NH4+-N removal in spent caustic wastewater treatment.