Abstract
For a long time, transition metal oxide systems have been considered well explored materials in heterogeneous catalysis. Amongst, the spinel-type oxides, materials such as cobaltites (Co3O4) received significant attention, owing to their use in many industrial applications. In the present study, nanosized Cu, Ni, and Zn cobaltite spinel oxides were synthesized by a simple hydrothermal method. Physicochemical characterization of the synthesized materials was performed utilizing XRD, HRTEM, CO2-TPD, and XPS techniques. The textural characteristics (BET-surface area, pore size, etc.) of samples were determined from N2 physisorption measurements at −196 °C. The CO2-electrocatalytic reduction was selected as a model reaction to evaluate the electrochemical performance of the synthesized spinel cobaltites. For Ni, Cu, and Zn spinel materials, hydrogen was produced as the main product at the whole potential, along with other products, such as CO and HCOOH. Despite the advantages, the catalytic electrochemical CO2 reduction performance of spinel cobaltite catalysts is still far from adequate, which is principally ascribed to the low number of active sites combined with poor electrical conductivity.
Funder
Ministry of Education, Saudi Arabia
Subject
Physical and Theoretical Chemistry,Catalysis,General Environmental Science
Cited by
7 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献