Abstract
Controllable linear actuation of polypyrrole (PPy) is the envisaged goal where only one ion dominates direction (here anions) in reversible redox cycles. PPy with polyethylene oxide (PEO) doped with dodecylbenzenesulfonate forms PPy-PEO/DBS films (PPy-PEO), which are applied in propylene carbonate (PC) solvent with electrolytes such as 1-ethyl-2,3-dimethylimidazolium trifluoromethanesulfonate (EDMICF3SO3), sodium perchlorate (NaClO4) and tetrabutylammonium hexafluorophosphate (TBAPF6) and compared in their linear actuation properties with pristine PPy/DBS samples. PPy-PEO showed for all applied electrolytes that only expansion at oxidation appeared in cyclic voltammetric studies, while pristine PPy/DBS had mixed-ion actuation in all electrolytes. The electrolyte TBAPF6-PC revealed for PPy-PEO best results with 18% strain (PPy/DBS had 8.5% strain), 2 times better strain rates, 1.8 times higher electronic conductivity, 1.4 times higher charge densities and 1.5 times higher diffusion coefficients in comparison to PPy/DBS. Long-term measurements up to 1000 cycles at 0.1 Hz revealed strain over 4% for PPy-PEO linear actuators, showing that combination of PPy/DBS with PEO gives excellent material for artificial muscle-like applications envisaged for smart textiles and soft robotics. FTIR and Raman spectroscopy confirmed PEO content in PPy. Electrochemical impedance spectroscopy (EIS) of PPy samples revealed 1.3 times higher ion conductivity of PPy-PEO films in PC solvent. Scanning electron microscopy (SEM) was used to investigate morphologies of PPy samples, and EDX spectroscopy was conducted to determine ion contents of oxidized/reduced films.
Subject
General Materials Science
Cited by
1 articles.
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