Cationic Lignocellulose Nanofibers from Agricultural Waste as High-Performing Adsorbents for the Removal of Dissolved and Colloidal Substances

Abstract

The accumulation of dissolved and colloidal substances (DCS) in the increasingly closed paper circulating water system can seriously lower the productivity and safety of papermaking machines, and it has been a challenge to develop an adsorbent with low cost, high adsorption efficiency and large adsorption capacity for DCS removal. In this study, cationic lignocellulose nanofibers (CLCNF) were obtained by cationic modification of agricultural waste bagasse in deep eutectic solvents (DES) followed by mechanical defibrillation, and then CLCNF were employed as an adsorbent for DCS model contaminant polygalacturonic acid (PGA) removal. CLCNF was characterized by transmission electron microscopy, Fourier transform infrared, elemental analysis, X-ray diffraction, and thermogravimetric analysis. The analytical results confirmed the successful preparation of CLCNF with 4.6–7.9 nm diameters and 0.97–1.76 mmol/g quaternary ammonium groups. The effects of quaternary ammonium group contents, pH, contact time and initial concentration of PGA on the adsorption were investigated in a batch adsorption study. According to the results, the cationic modification significantly enhanced the adsorption of PGA by CLCNF and the adsorption performance increased with the increase of the quaternary ammonium group contents. The adsorption of PGA on CLCNF followed the pseudo-second-order and the fitted Langmuir isotherm model. The adsorption showed fast initial kinetics and the experimental maximum adsorption capacity was 1054 mg/g, which is much higher than PGA adsorbents previously reported in the literature. Therefore, CLCNF with high cationic group content developed in this paper is a promising adsorbent for DCS removal.