Multi-Physical and Electrochemical Coupling Model for the Protonic Ceramic Fuel Cells with H+/e−/O2− Mixed Conducting Cathodes

Abstract

A protonic ceramic fuel cell (PCFC) has great potential for medium temperature power generation. Its working process, however, is complicated and quite different from the traditional oxygen ionic solid oxide fuel cell (O2−-SOFC) and proton exchange membrane fuel cell (PEMFC). In this paper, a multi-physical model for the PCFC with H+/e−/O2− mixed conducting cathode is established, in which the fuel- and oxidant-diffusing processes; electron-, oxygen ion-, and proton-conducting processes; three electrochemical reactions; and their coupling working details are carefully considered. Taking Ni-BZCY/BZCY/BZCY-LSCF PCFC as an example, the validation of the model is well verified by good agreements with the experiment iop-Vop curves at different temperatures. The result shows that the cathodic electrochemical reactions will be concentrated to a small thickness near the electrolyte because of the greatly decreased ionic conductivity compared with the high electronic conductivity at an intermediate temperature. O2− within the PCFC cathode is only an intermediate transform substance between the electrons and protons. Thus, there is a peak oxygen ion current distribution within the composite cathode of PCFC. The cathodic oxygen reduction half reaction is found to be a key factor to dominate the total PCFC voltage loss at the intermediate temperature zone. The concentration polarization of anode-supported PCFC is small, due to the vapors that are generated in the cathode side instead of anode side.