Interfacial Reaction and Electromigration Failure of Cu Pillar/Ni/Sn-Ag/Cu Microbumps under Bidirectional Current Stressing

Author:

Fu Zhiwei12ORCID,Chen Jian2,Zhao Pengfei3,Guo Xiaotong2ORCID,Xiao Qingzhong2,Fu Xing2ORCID,Wang Jian12,Yang Chao12,Xu Jile4,Yang Jia-Yue15ORCID

Affiliation:

1. School of Energy and Power Engineering, Shandong University, Jinan 250100, China

2. Science and Technology on Reliability Physics and Application of Electronic Component Laboratory, China Electronic Product Reliability and Environmental Testing Research Institute, Guangzhou 510610, China

3. School of Microelectronics, Xi’an Jiaotong University, Xi’an 710049, China

4. Jiaxing Key Laboratory of Flexible Electronics Based Intelligent Sensing and Advanced Manufacturing Technology, Institute of Flexible Electronics Technology of THU, Jiaxing 314000, China

5. Optics & Thermal Radiation Research Center, Institute of Frontier and Interdisciplinary Science, Shandong University, Qingdao 266237, China

Abstract

The electromigration behavior of microbumps is inevitably altered under bidirectional currents. Herein, based on a designed test system, the effect of current direction and time proportion of forward current is investigated on Cu Pillar/Ni/Sn-1.8 Ag/Cu microbumps. Under thermo-electric stressing, microbumps are found to be susceptible to complete alloying to Cu6Sn5 and Cu3Sn. As a Ni layer prevents the contact of the Cu pillar with the solder, Sn atoms mainly react with the Cu pad, and the growth of Cu3Sn is concentrated on the Cu pad sides. With direct current densities of 3.5 × 104 A/cm2 at 125 °C, the dissolution of a Ni layer on the cathode leads to a direct contact reaction between the Cu pillar and the solder, and the consumption of the Cu pillar and the Cu pad shows an obvious polarity difference. However, with a bidirectional current, there is a canceling effect of an atomic electromigration flux. With current densities of 2.5 × 104 A/cm2 at 125 °C, as the time proportion of the forward current approaches 50%, a polarity structural evolution will be hard to detect, and the influence of the chemical flux on Cu-Sn compounds will be more obvious. The mechanical properties of Cu/Sn3.0Ag0.5Cu/Cu are analyzed at 125 °C with direct and bidirectional currents of 1.0 × 104 A/cm2. Compared with high-temperature stressing, the coupled direct currents significantly reduced the mechanical strength of the interconnects, and the Cu-Sn compound layers on the cathode became the vulnerable spot. While under bidirectional currents, as the canceling effect of the electromigration flux intensifies, the interconnect shear strength gradually increases, and the fracture location is no longer concentrated on the cathode sides.

Funder

National Key R&D Program of China

the Development Fund of the China Electronic Product Reliability and Environmental Testing Research Institute

National Natural Science Foundation of China

Guangdong Basic and Applied Basic Research Foundation

Publisher

MDPI AG

Subject

General Materials Science

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