Application of Portable CH4 Detector Based on TDLAS Technology in Natural Gas Purification Plant

Author:

Liu Yi1,Shang Qianqian2,Chen Lang2,Wang Erxiao1,Huang Xinyu1,Pang Xiaobing2,Lu Youhao2,Zhou Lei2,Zhou Jue2,Wang Zhiwen2,Lyu Yan2

Affiliation:

1. Safety, Environment and Technology Supervision Research Institute of PetroChina Southwest Oil and Gas Field Company, Chengdu 610041, China

2. College of Environment, Zhejiang University of Technology, Hangzhou 310014, China

Abstract

Methane (CH4) is the main pollutant in oil and gas production. The detection and accounting of CH4 is an important issue in the process of greenhouse gas control and emission reduction in oil and gas industry. In this study, a portable CH4 detector based on tunable diode laser absorption spectroscopy (TDLAS) technology was deployed. The three-dimensional distribution of CH4 in a natural gas purification plant in Sichuan was obtained through vertical unmanned aerial vehicle (UAV) flight observations and ground mobile observations. According to the mass balance method, the emission of CH4 on 30 m above ground level (AGL) and 60 m AGL in this site was about 0.012 kg/s (±42% at 1σ) and 0.034 kg/s (±47% at 1σ), respectively, in one day. The vertical distribution showed that the CH4 concentration reached the maximum (2.75 ± 0.19 ppm) with height of 0 to 100 m AGL. The CH4 concentration from 100 to 300 m AGL showed a downward trend with height. Atmospheric instability at high altitude and high wind speed promoted the diffusion of CH4. The CH4 concentrations of horizontal distribution on 30 m AGL and 60 m AGL were 2.48 ± 0.11 ppm and 2.76 ± 0.34 ppm. In the observation of mobile campaigns, the connecting equipment of natural gas treatment facilities was prone to leakage, such as in valves and flanges. CH4 leakage was also detected at the torch mouth, especially when there was an open flame at the torch mouth. During the mobile movement investigation, the downwind measurement (OTM-33A) was applied to determine the overall CH4 emission rate shortly after patrolling the site. This work plays a vital role in optimizing the operation and maintenance of natural gas production stations pipe network, ensuring human safety and minimizing greenhouse gas emissions.

Funder

National Natural Science Foundation of China

Chongqing Technological Innovation and Application Development Special Key Project

Zhejiang Province Lingyan Research and Development Project

Shaoxing Science and Technology Plan Project

Publisher

MDPI AG

Subject

Atmospheric Science,Environmental Science (miscellaneous)

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