Archaeometric Investigations of the Chalcolithic Pottery from Topolița—Neamț County, Romania
Author:
Ion Rodica-Mariana12ORCID, Diaconu Vasile3, Vasilievici Gabriel1ORCID, Iancu Lorena1, Grigorescu Ramona Marina1ORCID, Mîrț Luiza-Andreea1ORCID, Alexandrescu Elvira1, Gheboianu Anca Irina4ORCID, Slamnoiu-Teodorescu Sofia4
Affiliation:
1. National Institute for Research & Development in Chemistry and Petrochemistry—ICECHIM, Research Group ‘Evaluation and Conservation of Cultural Heritage’, 202 Splaiul Independentei, 060021 Bucharest, Romania 2. Doctoral School of Materials Engineering Department, “Valahia” University of Targoviste, 35 Lt. Stancu Ion, 130105 Targoviste, Romania 3. Museum of History and Ethnography Târgu Neamț/Neamț County Museum Complex, 37 Ștefan cel Mare St., 615200 Târgu Neamt, Romania 4. Institute of Multidisciplinary Research for Science and Technology, Valahia University of Targoviste, 130004 Targoviste, Romania
Abstract
The current work deals with specific investigations on the ceramic fragment samples from the archaeological site of Topolița (Eastern Romania), which is essentially unexplored to date. X-ray diffraction (XRD) has shown that the ceramics contain quartz, berlinite, mica (muscovite), calcite, and opaque minerals, such as hematite. All evidence indicates the use of raw materials with a low limestone content (poor Ca clays) for the manufacture of these ceramics (Ca < 3.6%). The wavelength dispersive X-ray fluorescence (WDXRF) measurements indicated the presence of Al, Si, Fe, Ca, Zn, P, and K. All these data are well correlated with energy dispersive spectroscopy (EDS), which is used as an additional technique of scanning electron microscopy (SEM). Through thermogravimetry and porosimetry, some information have been obtained, with the results being correlated with the chromatic parameters that characterize the samples after burning: Various shades of color (red color with sparkles and partially or totally black interior), differently colored engobes, white pigment encrusted with white color from calcite, gypsum, clays, and quartz, as well as carbon deposits in the pores of the pottery, all specific to the Chalcolithic ceramics from this region. The recorded FTIR spectra of these samples led to the identification of calcite, quartz, gypsum, and aluminum phosphate, present as berlinite in all the pottery specific to this area. In addition, the presence/absence and the amount of specific chemical elements in the white pigments (e.g., calcium, aluminum, phosphorus, silicon, sulfur) could be used as indicative for the identified mineral compounds (XRD and FTIR). Calcite and silica-rich sediments as the primary decoration pigments, have been identified in this case.
Funder
UEFISCDI-MCID, Romania
Subject
Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces
Reference43 articles.
1. Technological features of the chalcolithic pottery from Târpești (Neamț County, Eastern Romania);Pintilei;Mediterr. Archaeol. Archaeom.,2019 2. Recunoașteri arheologice de suprafaţă în zona orașului Târgu Neamţ;Diaconu;Mem. Antiq.,2007 3. Preoteasa, C., Diaconu, V., Mischka, D., Mischka, C., Praschl, B., Schaffer, M., Wanka, F., and Gapp, F. (2017). Topolița, com. Grumăzești, jud. Neamț. Punct: La Nord-Vest de Sat, in Cronica Cercetărilor Arheologice din România. Campania 2016, Institutul Național al Patrimoniului. 4. Diaconu, V., Gafincu, A.-M., Hanceanu, G.D., Nicola, C.-D., Preoteasa, C., Stiglet, D.-I., and Pirnau, R. (2019). Topolița, com. Grumăzești, jud. Neamț. Punct: La Nord-Vest de sat, in Cronica Cercetărilor Arheologice din România. Campania 2018, Institutul Național al Patrimoniului. 5. Insights into the Phaeozems pedogenesis using total elemental composition analysis. A case study from north-eastern Romania;Patriche;Geoderma,2022
Cited by
3 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
|
|