Perspective Coatings Based on Structured Conducting ITO Thin Films for General Optoelectronic Applications

Author:

Toikka Andrei1234ORCID,Ilin Matwei1234,Kamanina Natalia1234

Affiliation:

1. Lab for Photophysics of Nanostructured Materials and Devices, Joint Stock Company Scientific and Production Corporation S.I. Vavilov State Optical Institute, Babushkina Str. 1, 192171 St. Petersburg, Russia

2. Lab for Photophysics of Media with Nanoobjects, Vavilov State Optical Institute, Kadetskaya Liniya V.O., dom 5, korp. 2, 199053 St. Petersburg, Russia

3. Department of Photonics, St.-Petersburg Electrotechnical University (“LETI”), Ul. Prof. Popova, dom 5, 197376 St. Petersburg, Russia

4. Department of Advanced Development, Petersburg Nuclear Physics Institute, National Research Center “Kurchatov Institute”, 1 md. Orlova Roshcha, 188300 Gatchina, Russia

Abstract

In many electro-optical devices, the conductive layer is an important key functional element. Among others, unique indium tin oxide (ITO) contacts take priority. ITO structure is widely used as the optical transparent and electrically conductive material in general optoelectronics, biosensors and electrochemistry. ITO is one of the key elements in the liquid crystal (LC) displays, spatial light modulators (SLMs) and LC convertors. It should be mentioned that not only the morphology of this layer structure but also the surface features play an important role in the study of the physical parameters of the ITO. In order to switch the surface properties (roughness, average tilt angle and surface free energy) of the ITO via the laser-oriented deposition (LOD) method, carbon nanotubes (CNTs) were implanted. In the LOD technique, the CO2 laser (λ = 10.6 μm, P = 30 W) with the control electric grid was used. The switching of the deposition conditions was provided via the varying electrical strength of the control grid in the range of 100–600 V/cm. The diagnostics of the surfaces were performed using AFM analysis and wetting angle measurements. The components of the surface free energy (SFE) were calculated using the OWRK method. The main experimental results are as follows: the roughness increases with a rise in the electric field strength during the deposition of the CNTs; the carbon nanotubes provide a higher level of the dispersive component of SFE (25.0–31.4 mJ/m2 against 22.2 mJ/m2 in the case of pure ITO); the CNTs allow an increase in the wetting angle of the 5CB liquid crystal drops from 38.35° to 58.95°. Due to the possibility of the switching properties of the ITO/CNT surfaces, these modifications have potential interest in microfluidics applications and are useful for the liquid crystal’s electro-optics.

Funder

Russian Science Foundation

Publisher

MDPI AG

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces

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