Investigation of the Properties of Multilayer Nanostructured Coating Based on the (Ti,Y,Al)N System with High Content of Yttrium

Author:

Grigoriev Sergey1ORCID,Vereschaka Alexey2ORCID,Milovich Filipp3,Sitnikov Nikolay4,Bublikov Jury2,Seleznev Anton1ORCID,Sotova Catherine1ORCID,Rykunov Alexander5

Affiliation:

1. Department of High-Efficiency Processing Technologies (VTO), Moscow State University of Technology, STANKIN, Vadkovsky per. 1, 127055 Moscow, Russia

2. Institute of Design and Technological Informatics, Russian Academy of Sciences (IDTI RAS), 127055 Moscow, Russia

3. Materials Science and Metallurgy Shared Use Research and Development Center, National University of Science and Technology MISiS, Leninsky Prospect 4, 119049 Moscow, Russia

4. State Scientific Center, Russian Federation “Keldysh Research Center”, 8, Onezhskaya Str., 125438 Moscow, Russia

5. Federal State-Financed Educational Institution, High Professional Education P. A. Solovyov Rybinsk State Aviation Technical University, St. Pushkina, 53, 152934 Rybinsk, Russia

Abstract

The studies are focused on the properties of the multilayer composite coating based on the (Ti,Y,Al)N system with high content of yttrium (about 40 at.%) of yttrium (Y). The hardness and elastic modulus were defined, and the resistance to fracture was studied during the scratch testing. Two cubic solid solutions (fcc phases), including c-(Ti,Y,Al)N and c-(Y,Ti,Al)N, are formed in the coating. The investigation of the wear resistance of the (Ti,Y,Al)N-coated tools during the turning of steel in comparison with the wear resistance of the tools with the based on the (Ti,Cr,Al)N system coating and the uncoated tools found a noticeable increase (by 250%–270%) in rake wear resistance. Active oxidation processes are observed in the (Ti,Y,Al)N coating during wear. It can be assumed that yttrium oxide is predominantly formed with a possible insignificant formation of titanium and aluminum oxides. At the same time, complete oxidation of c-(Y,Ti,Al)N nanolayers is not observed. Some hypotheses explaining the rather high performance of a coating with a high yttrium content are considered.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

MDPI AG

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces

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