High Poisonous Cd Ions Removal by Ru-ZnO-g-C3N4 Nanocomposite: Description and Adsorption Mechanism

Author:

Ismail Mukhtar1,Albadri Abuzar2,Ben Aissa Mohamed Ali1,Modwi Abueliz1ORCID,Saleh Sayed M.23ORCID

Affiliation:

1. Department of Chemistry, College of Science and Arts, Qassim University, Ar-Rass 51921, Saudi Arabia

2. Department of Chemistry, College of Science, Qassim University, Buraidah 51452, Saudi Arabia

3. Chemistry Branch, Department of Science and Mathematics, Faculty of Petroleum and Mining Engineering, Suez University, Suez 43721, Egypt

Abstract

Ru-ZnO-g-C3N4 nanocomposite was made using a straightforward ultrasonication method and evaluated for its potential to remove Cd ions from aqueous environments. X-ray diffraction analysis confirms composite production with an average crystalline size of 6.61 nm, while transmission electron microscopy results indicate nanosheet-like nanomaterials with uniform elements distribution. Measurements of N2 adsorption–desorption reveal the creation of a mesoporous structure with a BET surface area of approximately 257 m2/g. Fourier converted infrared reveals vibrational modes for O-H, amino groups, triazine, and Ru-ZnO. In contrast, X-ray photoelectron spectroscopy investigation reveals the presence of the elements Ru, Zn, O, N, and C. Ru-ZnO-g-C3N4 nanocomposite has remarkable adsorption efficiency for aqueous Cd ions, achieving 475.5 mg/g in 18 min. This study reveals that the Ru-ZnO-g-C3N4 nanocomposite may be used as an effective and reusable adsorbent for removing Cd ions during wastewater treatment and, possibly, for eliminating other toxic metal ions.

Funder

Deputyship for Research & Innovation, Ministry of Education, Saudi Arabia

Publisher

MDPI AG

Subject

Inorganic Chemistry

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