Enhancement of Wood Coating Properties by Adding Silica Sol to UV-Curable Waterborne Acrylics

Author:

Zhu Yuding1,Zhu Wenkai1ORCID,Li Zequn1,Feng Yuan2ORCID,Qi Wei1,Li Song1,Wang Xiaoyu3,Chen Meiling2ORCID

Affiliation:

1. College of Chemistry and Materials Engineering, Zhejiang A&F University, Hangzhou 311300, China

2. Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China

3. Jiangsu Key Laboratory for Biomass-Based Energy and Enzyme Technology, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai’an 223300, China

Abstract

In recent years, with the development of the coating industry and the increasing awareness of environmental protection, the modification of waterborne wood coatings has become the focus of research. Generally, the system composed of silica sol modification and UV curing can make up for the defects of poor mechanical properties, low hardness, and slow curing speeds of waterborne wood coatings. Herein, we used silica sol-reinforced UV-curable waterborne acrylic wood coatings and tested the related physical properties of the coatings. FT-IR analysis showed that the Si-O-Si bond appeared, indicating that the silica sol was successfully grafted onto the waterborne acrylic molecular chain. The results showed that the mechanical properties of the UV-curable waterborne acrylic wood coating film reached their optimum when the content of silica sol was 1 wt%, the number of UV lamps was 3, and the drying time was 20 min. The corresponding values for wear resistance, hardness, adhesion, and impact strength were 0.106 g (high level), grade 3, and 90 kg·cm, respectively. However, when the content of silica sol is greater than 1 wt%, the related physical properties of the coatings will decrease. The results showed that the gloss of the coating decreased with increasing silica sol content. When the silica sol content was 2 wt%–6 wt%, the coating showed a matte gloss. This present work shows that the modification process is simple, controlled, inexpensive, and meets the demand for UV-curable waterborne acrylic wood coatings in daily life.

Funder

Nanjing Science and Technology Innovation Project

Research and Development Funding of Zhejiang A&F University

Natural Science Foundation of Jiangsu Province of China

National Natural Science Foundation of China

Natural Science Foundation of the Higher Education Institutions of Jiangsu Province

Publisher

MDPI AG

Subject

Forestry

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