Microfibrillated Cellulose Suspension and Its Electrorheology

Abstract

Microfibrillated cellulose (MFC) particles were synthesized by a low-pressure alkaline delignification process, and their shape and chemical structure were investigated by SEM and Fourier transformation infrared spectroscopy, respectively. As a novel electrorheological (ER) material, the MFC particulate sample was suspended in insulating oil to fabricate an ER fluid. Its rheological properties—steady shear stress, shear viscosity, yield stress, and dynamic moduli—under electric field strength were characterized by a rotational rheometer. The MFC-based ER fluid demonstrated typical ER characteristics, in which the shear stresses followed the Cho–Choi–Jhon model well under electric field strength. In addition, the solid-like behavior of the ER fluid was investigated with the Schwarzl equation. The elevated value of both dynamic and elastic yield stresses at applied electric field strengths was well described using a power law model (~E1.5). The reversible and quick response of the ER fluid was also illustrated through the on–off test.