Ecological Risk Assessment of Heavy Metals in Adjoining Sediment of River Ecosystem

Abstract

The present study was focused on heavy metal distribution patterns and the associated ecological risk assessment in the adjoining sediment of the Hindon River in Muzaffarnagar Region (U.P.), India. Lead (Pb), zinc (Zn), copper (Cu), cadmium (Cd), nickel (Ni), iron (Fe), aluminum (Al), sodium (Na), and potassium (K) were estimated from six sediment samples (Atali A and B, Budhana A and B, and Titavi A and B). The concentration of the heavy metals Zn, Pb, Cu, Ni, and Cd ranged from 25.5–74.7 mg kg−1, 29.8–40.6 mg kg−1, 7.0–29.2 mg kg−1, 14.7–21.8 mg kg−1, and 0.96–1.2 mg kg−1, respectively and followed the sequence Zn > Pb > Cu > Ni > Cd, while major elements followed the sequence Na > Fe > Al > K. The enrichment factor (EF) and geo-accumulation index (Igeo) revealed that Atali A showed the highest enrichment and followed the sequence Zn > Cu > Pb > Ni > Cd. Contamination factor (CF) and contamination degree (CD) depicted that all of the sites (except Titavi B) were moderately to considerably contaminated. The highest degree of contamination (CF, CD, and PLI, pollution load index) was observed at Titavi A followed by Atali A and Budhana A. Eco-toxicological risk assessment (RI) indicated that the sites were moderately contaminated, predominantly by Ni and Pb and Zn. The results revealed that the metal contamination in sediment is alarming and might pose an adverse threat to ecosystem health.