Influence of Quaternary Ammonium Salt Functionalized Chitosan Additive as Sustainable Filler for High-Density Polyethylene Composites

Abstract

In this study, an antimicrobial packaging material was successfully developed with blends of high-density polyethylene (HDPE) and chitosan (CS) made by melt processing. In the different HDPE/CS composites, the CS content effect (up to 40%), and the addition of quaternary ammonium salt functionalized chitosan (CS-CTAB) as an additive were evaluated by X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analyses (TG), tensile strength, scanning electron microscopy (SEM) and antimicrobial activity. When analyzing the effect of the additive in the different HDPE/CS composites, it was observed that the compositions with 10 and 20 %wt of chitosan showed better elongation values (~13% and 10%) as well as a higher decomposition temperature at 20% mass loss (T20) varying from (321–332 °C and 302–312 °C), respectively, in relation to the other compositions, regardless of the type of additive used, it acted as an antimicrobial agent, promoting inhibition of microbial growth against the strains gram-positive and gram-negative used in this work, making the different HDPE/CS composites suitable candidates for use in food packaging.