Author:
Gu Jinzhong,Wen Min,Liang Xiaoxiao,Shi Zifa,Kirillova Marina,Kirillov Alexander
Abstract
Selected recent examples of coordination polymers (CPs) or metal-organic frameworks (MOFs) constructed from different multifunctional carboxylic acids with phenyl-pyridine or biphenyl cores have been discussed. Despite being still little explored in crystal engineering research, such types of semi-rigid, thermally stable, multifunctional and versatile carboxylic acid building blocks have become very promising toward the hydrothermal synthesis of metal-organic architectures possessing distinct structural features, topologies, and functional properties. Thus, the main aim of this mini-review has been to motivate further research toward the synthesis and application of coordination polymers assembled from polycarboxylic acids with phenyl-pyridine or biphenyl cores. The importance of different reaction parameters and hydrothermal conditions on the generation and structural types of CPs or MOFs has also been highlighted. The influence of the type of main di- or tricarboxylate ligand, nature of metal node, stoichiometry and molar ratio of reagents, temperature, and presence of auxiliary ligands or templates has been showcased. Selected examples of highly porous or luminescent CPs, compounds with unusual magnetic properties, and frameworks for selective sensing applications have been described.
Funder
National Natural Science Foundation of China
Foundation for Science and Technology
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering
Reference69 articles.
1. Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013)
2. The Chemistry of Metal-Organic Frameworks: Synthesis, Characterization, and Applications,2016
3. Functional Supramolecular Materials: From Surfaces to MOFs,2017
4. Metal-Organic Framework Materials,2014
5. Metal-Organic Frameworks: Applications from Catalysis to Gas Storage,2011
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