Application of Stable Isotope Techniques in Tracing the Sources of Atmospheric NOX and Nitrate

Abstract

Nitrate is an important component of PM2.5, and its dry deposition and wet deposition can have an impact on ecosystems. Nitrate in the atmosphere is mainly transformed by nitrogen oxides (NOX = NO + NO2) through a number of photochemical processes. For effective management of the atmosphere’s environment, it is crucial to understand the sources of atmospheric NOX and the processes that produce atmospheric nitrate. The stable isotope method is an effective analytical method for exploring the sources of NO3− in the atmosphere. This study discusses the range and causes of δ15N data from various sources of NOX emissions, provides the concepts of stable isotope techniques applied to NOX traceability, and introduces the use of Bayesian mixture models for the investigation of NOX sources. The combined application of δ15N and δ18O to determine the pathways of nitrate formation is summarized, and the contribution of Δ17O to the atmospheric nitrate formation pathway and the progress of combining Δ17O simulations to reveal the atmospheric oxidation characteristics of different regions are discussed, respectively. This paper highlights the application results and development trend of stable isotope techniques in nitrate traceability, discusses the advantages and disadvantages of stable isotope techniques in atmospheric NOX traceability, and looks forward to its future application in atmospheric nitrate pollution. The research results could provide data support for regional air pollution control measures.