Prognostic Assessment of the Viability of Hydrothermal Liquefaction as a Post-Resource Recovery Step after Enhanced Biomethane Generation Using Co-Digestion Technologies

Abstract

In line with global efforts at encouraging paradigm transitions from waste disposal to resource recovery, the anaerobic co-digestion of substrates of wet hydrolyzed meat processing dissolved air flotation sludge and meat processing stock yard waste was investigated in the present study. It was demonstrated that the co-digestion of these substrates leads to the introduction of co-digestion synergizing effects. This study assessed biomethane potentials of the co-digestion of different substrate mixtures, with the preferred substrate mixture composed of stockyard waste and wet hydrolyzed meat processing dissolved air flotation sludge, present in a 4:1 ratio on a volatile solid mass basis. This co-digestion substrate mix ratio presented an experimentally determined cumulative biomethane potential of 264.13 mL/gVSadded (volatile solid). The experimentally determined cumulative biomethane potential was greater than the predicted maximum cumulative biomethane potential of 148.4 mL/gVSadded, anticipated from a similar substrate mixture if synergizing effects were non-existent. The viability of integrating a downstream hydrothermal liquefaction processing of the digestate residue from the co-digestion process, for enhanced resource recovery, was also initially assessed. Assessments were undertaken via the theoretical based estimation of the yields of useful products of biocrude and biochar obtainable from the hydrothermal liquefaction processing of the digestate residue. The environmental sustainability of the proposed integrated system of anaerobic digestion and hydrothermal liquefaction technologies was also initially assessed. The opportunity for secondary resource recovery from the digestate, via the employment of the hydrothermal liquefaction process and the dependence of the environmental sustainability of the integrated system on the moisture content of the digestate, were established. It is anticipated that the results of this study will constitute an invaluable basis for the future large-scale implementation of the proposed integrated system for enhanced value extraction from organic waste streams.