Determination of Thermal Damage Threshold in THz Photomixers Using Raman Spectroscopy

Author:

Mikulics Martin12,Adam Roman3,Chen Genyu4,Chakraborty Debamitra4,Cheng Jing4,Pericolo Anthony5,Komissarov Ivan5,Bürgler Daniel E.3ORCID,Heidtfeld Sarah F.3,Serafini John6,Preble Stefan6,Sobolewski Roman45ORCID,Schneider Claus M.3ORCID,Mayer Joachim12,Hardtdegen Hilde H.12ORCID

Affiliation:

1. Ernst-Ruska-Centre (ER-C-2), Forschungszentrum Jülich, 52425 Jülich, Germany

2. Jülich-Aachen Research Alliance (JARA), Fundamentals of Future Information Technology, 52425 Jülich, Germany

3. Peter Grünberg Institute (PGI-6), Forschungszentrum Jülich, 52425 Jülich, Germany

4. Materials Science Program and Laboratory for Laser Energetics, University of Rochester, Rochester, NY 14627, USA

5. Department of Electrical and Computer Engineering and Laboratory for Laser Energetics, University of Rochester, Rochester, NY 14627, USA

6. Rochester Institute of Technology, Rochester, NY 14623, USA

Abstract

The increase of device lifetime and reliability of THz photomixers will play an essential role in their possible future application. Therefore, their optimal work conditions/operation range, i.e., the maximal incident optical power should be experimentally estimated. We fabricated and tested THz photomixer devices based on nitrogen-implanted GaAs integrated with a Bragg reflector. Raman spectroscopy was applied to investigate the material properties and to disclose any reversible or irreversible material changes. The results indicate that degradation effects in the photomixer structures/material could be avoided if the total optical power density does not exceed levels of about 0.7 mW/µm2 for 100 min of operation. Furthermore, the investigations performed during 1000 min of optical exposure on the photomixer devices’ central region comprising interdigitated metal-semiconductor-metal (MSM) structures suggest a reversible “curing” mechanism if the power density level of ~0.58 mW/µm2 is not exceeded. Long-term operation (up to 1000 h) reveals that the photomixer structures can withstand an average optical power density of up to ~0.4 mW/µm2 without degradation when biased at 10 V. Besides the decrease of the position of the A1g (LO) Raman mode from ~291 cm−1 down to ~288 cm−1 with increasing optical power density and operation time, broad Raman modes evolve at about 210 cm−1, which can be attributed to degradation effects in the active photomixer/MSM area. In addition, the performed carrier lifetime and photomixer experiments demonstrated that these structures generated continuous wave sub-THz radiation efficiently as long as their optimal work conditions/operation range were within the limits established by our Raman studies.

Funder

U.S. Department of Energy

Publisher

MDPI AG

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering

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