Spatial Self-Phase Modulation in Graphene-Oxide Monolayer

Abstract

The spatial self-phase modulation (SSPM) of the optical field revealed the magnitude and polarity of nonlinear refraction coefficients of the graphene-oxide (GO) atomic layers in an aqueous base solution with a resonant excitation using a chopped quasi-static laser at 532 nm. The SSPM of the optical field as a result of the intrinsic nonlinear refraction coefficient of GO atomic layers and the spatial distribution of intensity displayed the concentric diffraction rings at the far field due to the coherent superposition of transverse wave vectors. The number of concentric rings as a function of the applied intensity revealed the nonlinear refraction coefficient of GO which was estimated to be ~–6.65 × 10−12 m2/W for the laser-excitation duration of ~0.32 s, where the negative polarity of nonlinear refraction coefficient was confirmed with the interference image profile of SSPM. The upper and vertical distortion of concentric rings at the far field at the longer laser-excitation duration of ~0.8 s indicates the distortion of the coherent superposition of transverse wave vectors due to the localized thermal vortex of GO in the aqueous solution that offers novel platforms of thermal metrology based on localized optical nonlinearity and temperature-sensitive all-optical switching.