Removal of Phenol from Aqueous Solution Using Internal Microelectrolysis with Fe-Cu: Optimization and Application on Real Coking Wastewater

Abstract

Fe-Cu materials were synthesized using the chemical plating method from Fe powder and CuSO4 5% solution and then characterized for surface morphology, composition and structure by scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD), respectively. The as-synthesized Fe-Cu material was used for removal of phenol from aqueous solution by internal microelectrolysis. The internal electrolysis-induced phenol decomposition was then studied with respect to various parameters such as pH, time, Fe-Cu material weight, phenol concentration and shaking speed. The optimal phenol decomposition (92.7%) was achieved under the conditions of (1) a pH value of phenol solution of 3, (2) 12 h of shaking at the speed of 200 rpm, (3) Fe-Cu material weight of 10 g/L, (4) initial phenol concentration of 100.98 mg/L and (5) at room temperature (25 ± 0.5 °C). The degradation of phenol using Fe-Cu materials obeyed the second-order apparent kinetics equation with a reaction rate constant of k of 0.009 h−1L mg−1. The optimal process was then tested against real coking wastewater samples, resulting in treated wastewater with favorable water indicators. Current findings justify the use of Fe-Cu materials in practical internal electrolysis processes.