Large Eddy Simulation and Thermodynamic Design of the Organic Rankine Cycle Based on Butane Working Fluid and the High-Boiling-Point Phenyl Naphthalene Liquid Heating System

Abstract

Large Eddy Simulation (LES) and Thermodynamic study have been performed on Organic Rankine Cycle (ORC) components (boiler, evaporator, turbine, pump, and condenser). The petroleum Coke burner provided the heat flux needed for the butane evaporator. High boiling point fluid (called phenyl-naphthalene) has been applied in the ORC. The high boiling liquid is safer (steam explosion hazard may be prevented) for heating the butane stream. It has best exergy efficiency. It is non-corrosive, highly stable, and flammable. Fire Dynamics Simulator software (FDS) has been applied in order to simulate the pet-coke combustion and calculate the Heat Release Rate (HRR). The maximal temperature of the 2-Phenylnaphthalene flowing in the boiler is much less than its boiling temperature (600 K). Enthalpy, entropy and specific volume required for evaluating the heat rates and the power have been computed by employing the THERMOPTIM thermodynamic code. The proposed design ORC is safer. This is because the flammable butane is separated from the flame produced in the petroleum coke burner. The proposed ORC obeys the two fundamental laws of thermodynamics. The calculated net power is 3260 kW. It is in good agreement with net power is reported in the literature. The thermal efficiency of the ORC is 18.0%.