Adsorption Equilibrium of CO2 on Microporous Activated Carbon Produced from Avocado Stone Using H2SO4 as an Activating Agent

Author:

Siemak Joanna1,Michalkiewicz Beata1ORCID

Affiliation:

1. Department of Catalytic and Sorbent Materials Engineering, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, Piastów Ave. 42, 71-065 Szczecin, Poland

Abstract

In this study, we conducted a comprehensive investigation into activated carbons derived from avocado stones produced through chemical activation using sulfuric acid. The analysis encompassed X-ray diffraction (XRD) spectra, FTIR, SEM and essential textural parameters, namely specific surface area, total pore volume, and micropore volume. Moreover, we scrutinized carbon dioxide adsorption isotherms and subjected the experimental data to fit with both two-parameter and four-parameter equilibrium isotherm models. To achieve the most accurate parameter estimation, five error functions were employed. Furthermore, we calculated the isosteric heat of adsorption for the most promising CO2 sorbent, providing valuable insights into the thermodynamic aspects of the adsorption process.

Publisher

MDPI AG

Subject

Management, Monitoring, Policy and Law,Renewable Energy, Sustainability and the Environment,Geography, Planning and Development,Building and Construction

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