Safeguarding Cork’s Beauty and Longevity: Innovations in Deposition of Protective Thin Films

Author:

Tiss Belgacem1,Martínez-Martínez Diego12ORCID,Mansilla Catalina3,Borges Joel1ORCID,Andritschky Martin1,Cunha Luís1ORCID

Affiliation:

1. Physics Center of Minho and Porto Universities (CF-UM-UP), Campus de Gualtar, 4710-057 Braga, Portugal

2. Luxembourg Institute of Science and Technology, Esch-sur-Alzette, 4362 Luxembourg, Luxembourg

3. CTECHnano Coatings Technologies S.L., Tolosa Hiribidea 76, 20018 San Sebastián, Spain

Abstract

Cork is a sustainable natural material widely used as a wine stopper. However, some other uses, such as wall coverings, flooring, bags and shoes, face UV damage. To mitigate this issue, we explored the deposition of TiO2 and ZnO thin films via magnetron sputtering on glass and cork substrates. Both films displayed uniformity and the lack of any discernible cracks or voids, remained transparent in the visible region, and offered UV protection. Thus, TiO2 and ZnO blocked UV light with a wavelength of up to 310 nm (Eg = 4 eV) and 370 nm (Eg = 3.3 eV), respectively. Exposure tests, under a sun simulator lamp, revealed that the uncoated cork showed noticeable color changes, even when located under a glass substrate. The TiO2 coating did not prevent cork discoloration, while ZnO prevented it. This study highlights ZnO thin films as a durable solution to safeguard cork materials from UV damage and extend their usability.

Funder

the Portuguese Foundation for Science and Technology

Publisher

MDPI AG

Subject

Management, Monitoring, Policy and Law,Renewable Energy, Sustainability and the Environment,Geography, Planning and Development,Building and Construction

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