Abstract
Hydrogen transfer reactions have exceptional importance, due to their applicability in numerous synthetic pathways, with academic as well as industrial relevance. The most important transformations are, e.g., reduction, ring-closing, stereoselective reactions, and the synthesis of heterocycles. The present review provides insights into the hydrogen transfer reactions in the condensed phase in the presence of noble metals (Rh, Ru, Pd) as catalysts. Since the H-donor molecules (such as alcohols/ethers and amines (1°, 2°, 3°)) and the acceptor molecules (alkenes (C=C), alkynes (C≡C), and carbonyl (C=O) compounds) play a crucial role from mechanistic viewpoints, the present summary points out the key mechanistic differences with the interpretation of current contributions and the corresponding historical achievements as well.
Subject
Physical and Theoretical Chemistry,Catalysis
Reference98 articles.
1. Transfer hydrogenation including the Meerwein-Ponndorf-Verley reduction;Klomp,2007
2. Hydrogen transfer in organic and organometallic reactions,2007
3. Ein neues Verfahren zur Reduktion von Aldehyden und Ketonen
4. The exchange of functional groups between two molecules. The passage of ketones to alcohols and the reverse;Verley;Bull. Soc. Chim. Fr.,1925
5. Der reversible Austausch der Oxydationsstufen zwischen Aldehyden oder Ketonen einerseits und primären oder sekundären Alkoholen anderseits
Cited by
69 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献