Modified Buckwheat Husk as a Filler for Urea–Formaldehyde Resin in Plywood Production

Author:

Kawalerczyk Jakub1ORCID,Walkiewicz Joanna1ORCID,Sedliačik Ján2ORCID,Dukarska Dorota1ORCID,Woźniak Magdalena3ORCID,Mirski Radosław1

Affiliation:

1. Department of Mechanical Wood Technology, Faculty of Forestry and Wood Technology, Poznań University of Life Sciences, 60-627 Poznań, Poland

2. Department of Furniture and Wood Products, Faculty of Wood Science and Technology, Technical University in Zvolen, 96053 Zvolen, Slovakia

3. Department of Chemistry, Faculty of Forestry and Wood Technology, Poznań University of Life Sciences, 60-627 Poznań, Poland

Abstract

The aim of the presented research was to determine the suitability of both non-modified and modified buckwheat husk (BH) as a filler for urea–formaldehyde adhesive in plywood production. The effect of two modification methods, acetylation and silanization, was investigated. Infrared spectroscopy outcomes confirmed that both acetylation and silanization of the filler had occurred. Based on the results, it was found that the introduction of BH had a significant effect on both the adhesive properties and the characteristics of the manufactured plywood. The application of non-modified husks led to a reduction in viscosity and an extension of the gelation time, and the produced plywood boards were characterized by reduced bonding quality and increased delamination. Modification of the husk surface by acetylation and silanization with 3-aminopropyltriethoxysilane contributed to the noticeable improvement in the resin properties. On the other hand, the improvement in plywood properties, consisting of the increase in bonding quality and reduced delamination, was observed only in the case of the silanized husk. Furthermore, the use of non-modified and acetylated husk did not significantly influence the formaldehyde emission. The reduction in the investigated emission of formaldehyde was observed only in the case of variants containing 15 and 20% of silanized buckwheat husk.

Funder

Faculty of Forestry and Wood Technology, Poznan University of Life Sciences

Slovak Research and Development Agency

Publisher

MDPI AG

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