Advantages of Bimetallic Organic Frameworks in the Adsorption, Catalysis and Detection for Water Contaminants

Author:

Luo Jun1,Luo Xiao1,Gan Yonghai1,Xu Xiaoming2,Xu Bin1,Liu Zhuang1,Ding Chengcheng1,Cui Yibin1,Sun Cheng13

Affiliation:

1. Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment of the People’s Republic of China, Nanjing 210042, China

2. Department of Chemistry, Tsinghua University, Beijing 100084, China

3. State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210023, China

Abstract

The binary metal organic framework (MOF) is composed of two heterometallic ions bonded to an organic ligand. Compared with monometallic MOFs, bimetallic MOFs have greatly improved in terms of structure, porosity, active site, adsorption, selectivity, and stability, which has attracted wide attention. At present, many effective strategies have been designed for the synthesis of bimetallic MOF-based nanomaterials with specific morphology, structure, and function. The results show that bimetallic MOF-based nanocomposites could achieve multiple synergistic effects, which will greatly improve their research in the fields of adsorption, catalysis, energy storage, sensing, and so on. In this review, the main preparation methods of bimetallic MOFs-based materials are summarized, with emphasis on their applications in adsorption, catalysis, and detection of target pollutants in water environments, and perspectives on the future development of bimetallic MOFs-based nanomaterials in the field of water are presented.

Funder

National Natural Science Foundation of China

National Key Research and Development Program: Stream System Ecological Buffer Interception, Filtration, and Purification Technology Research

Innovation Team Project of Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

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