A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area-Reference-Cited by-同舟云学术

A Chromium Terephthalate-Based Solid with Unusually Large Pore Volumes and Surface Area

Published:2005-09-23 Issue:5743 Volume:309 Page:2040-2042
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Férey G.¹²³⁴,Mellot-Draznieks C.¹²³⁴,Serre C.¹²³⁴,Millange F.¹²³⁴,Dutour J.¹²³⁴,Surblé S.¹²³⁴,Margiolaki I.¹²³⁴

Affiliation:

1. Institut Lavoisier, CNRS Unité Mixte de Recherche 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France.

2. Institut universitaire de France, 103, Boulevard Saint-Michel, 75005 Paris, France.

3. Royal Institution, 21 Albemarle Street, London W1S 4BS, UK.

4. European Radiation Synchotron Facility, 38042 Grenoble, France.

Abstract

We combined targeted chemistry and computational design to create a crystal structure for porous chromium terephthalate, MIL-101, withverylargeporesizes and surface area. Its zeotype cubic structure has a giant cell volume (∼702,000 cubic angstroms), a hierarchy of extra-large pore sizes (∼30 to 34 angstroms), and a Langmuir surface area for N 2 of ∼5900 ± 300 square meters per gram. Beside the usual properties of porous compounds, this solid has potential as a nanomold for monodisperse nanomaterials, as illustrated here by the incorporation of Keggin polyanions within the cages.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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