Phase Separation in the Double Perovskite Sr2FeNbO6-δ

Author:

Popov Daniil1,Batulin Ruslan2ORCID,Cherosov Mikhail2ORCID,Vagizov Farit2ORCID,Zinnatullin Almaz2ORCID,Chupakhina Tatiana3,Deeva Yuliya3ORCID,Maiti Tanmoy4,Eremina Rushana1ORCID

Affiliation:

1. Zavoisky Physical-Technical Institute, Federal Research Center “Kazan Scientific Center of RAS”, 420029 Kazan, Russia

2. Institute of Physics, Kazan (Volga Region) Federal University, 420008 Kazan, Russia

3. Institute of Solid State Chemistry of the Russian Academy of Sciences (UB), 620990 Yekaterinburg, Russia

4. Department of Materials Science and Engineering, Indian Institute of Technology, Kanpur 208016, India

Abstract

The ceramic perovskite Sr2FeNbO6-δ was synthesized via the solution combustion precursor method. X-ray phase analysis showed that the sample is single-phase and does not contain impurities. The specific heat capacity and the Mössbauer spectra were measured for the Sr2FeNbO6-δ ceramic in the temperature range of 4–300 K. The observation of an asymmetric doublet in the Mössbauer spectra and the literature data on the magnetic susceptibility indicated the presence of two magnetic subsystems in Sr2FeNbO6-δ with antiferromagnetic exchange interactions. Based on the analysis of the temperature dependence of the specific heat capacity, we determined the Debye and Einstein temperatures.

Funder

Russian Science Foundation

DST

Publisher

MDPI AG

Subject

Materials Chemistry,Chemistry (miscellaneous),Electronic, Optical and Magnetic Materials

Cited by 2 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. ESR and magnetization studies of double perovskite Sr2FeNbO6;Journal of Magnetism and Magnetic Materials;2023-12

2. Magnetic properties of the double perovskite Sr_2CoNbO_{6-δ};Magnetic resonance in solids;2023

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