Investigation of Different Pre-Treatment Techniques and 3D Printed Turbulence Promoter to Mitigate Membrane Fouling in Dairy Wastewater Module

Author:

Kertész Szabolcs1ORCID,Al-Tayawi Aws N.23ORCID,Gergely Gréta1ORCID,Ott Bence1,Gulyás Nikolett Sz.2,Jákói Zoltán12ORCID,Beszédes Sándor1ORCID,Hodúr Cecilia1,Szabó Tamás4ORCID,László Zsuzsanna1

Affiliation:

1. Department of Biosystems Engineering, Faculty of Engineering, University of Szeged, Moszkvai Krt. 9, H-6725 Szeged, Hungary

2. Doctoral School of Environmental Sciences, University of Szeged, Tisza Lajos Krt. 103, H-6725 Szeged, Hungary

3. Faculty of Environmental Science and Technology, University of Mosul, Al-Majmoa’a Street, Mosul 41002, Iraq

4. Department of Physical Chemistry and Materials Science, University of Szeged, Rerrich Béla Tér. 1, H-6720 Szeged, Hungary

Abstract

This study investigates the enhancement of dairy wastewater treatment using chemical and physical pre-treatments coupled with membrane separation techniques to reduce membrane fouling. Two mathematical models, namely the Hermia and resistance-in-series module, were utilized to comprehend the mechanisms of ultrafiltration (UF) membrane fouling. The predominant fouling mechanism was identified by fitting experimental data into four models. The study calculated and compared permeate flux, membrane rejection, and membrane reversible and irreversible resistance values. The gas formation was also evaluated as a post-treatment. The results showed that the pre-treatments improved UF efficiency for flux, retention, and resistance values compared to the control. Chemical pre-treatment was identified as the most effective approach to improve filtration efficiency. Physical treatments after microfiltration (MF) and UF showed better fluxes, retention, and resistance results than ultrasonic pre-treatment followed by UF. The efficacy of a three-dimensionally printed (3DP) turbulence promoter was also examined to mitigate membrane fouling. The integration of the 3DP turbulence promoter enhanced hydrodynamic conditions and increased the shear rate on the membrane surface, shortening filtration time and increasing permeate flux values. This study provides valuable insights into optimizing dairy wastewater treatment and membrane separation techniques, which can have significant implications for sustainable water resource management. The present outcomes clearly recommend the application of hybrid pre-, main- and post-treatments coupled with module-integrated turbulence promoters in dairy wastewater ultrafiltration membrane modules to increase membrane separation efficiencies.

Funder

Hungarian National Research, Development and Innovation Office

János Bolyai Research Scholarship of Hungarian Academy of Sciences

New National Excellence Program of the Ministry for Culture and Innovation from the Source of the National Research, Development and Innovation Fund

Publisher

MDPI AG

Subject

General Materials Science

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