Assessment of Thermochromic Packaging Prints’ Resistance to UV Radiation and Various Chemical Agents

Abstract

Thermochromic inks, also known as color changing inks, are becoming increasingly important for various applications that range from smart packaging, product labels, security printing, and anti-counterfeit inks to applications such as temperature-sensitive plastics and inks printed onto ceramic mugs, promotional items, and toys. These inks are also gaining more attention as part of textile decorations and can also be found in some artistic works obtained with thermochromic paints, due to their ability to change color when exposed to heat. Thermochromic inks, however, are known to be sensitive materials to the influence of UV radiation, heat fluctuations, and various chemical agents. Given the fact that prints can be found in different environmental conditions during their lifetime, in this work, thermochromic prints were exposed to the action of UV radiation and the influence of different chemical agents in order to simulate different environmental parameters. Hence, two thermochromic inks with different activation temperatures (one being cold and the other being body-heat activated), printed on two food packaging label papers that differ in their surface properties were chosen to be tested. Assessment of their resistance to specific chemical agents was performed according to the procedure described in the ISO 2836:2021 standard. Moreover, the prints were exposed to artificial aging to determine their durability when exposed to UV radiation. All tested thermochromic prints showed low resistance to liquid chemical agents as the color difference values were unacceptable in all cases. It was observed that the stability of thermochromic prints to different chemicals decreases with decreasing solvent polarity. Based on the results obtained after UV radiation, its influence in terms of color degradation is visible on both tested paper substrates, but more significant degradation was observed on the ultra-smooth label paper.