Recent Advances in the Application of Metal–Organic Frameworks for Polymerization and Oligomerization Reactions

Abstract

Polymers have become one of the major types of materials that are essential in our daily life. The controlled synthesis of value-added polymers with unique mechanical and chemical properties have attracted broad research interest. Metal–organic framework (MOF) is a class of porous material with immense structural diversity which offers unique advantages for catalyzing polymerization and oligomerization reactions including the uniformity of the catalytic active site, and the templating effect of the nano-sized channels. We summarized in this review the important recent progress in the field of MOF-catalyzed and MOF-templated polymerizations, to reveal the chemical principle and structural aspects of these systems and hope to inspire the future design of novel polymerization systems with improved activity and specificity.