Facile Strategy for Mass Production of Pt Catalysts for Polymer Electrolyte Membrane Fuel Cells Using Low-Energy Electron Beam

Abstract

There are so many variables affecting the large-scale chemical synthesis of nanoparticles that mass production remains a challenge. Here, using a high-efficiency compact electron beam generator irradiating a low-energy electron beam, we fabricate carbon-supported Pt nanoparticles (Pt/C) in an open chamber to present the applicability of an electron beam to the mass production of metal nanocatalysts for polymer electrolyte membrane fuel cells (PEMFCs). The amount of dispersants (glycerol) and radical scavengers (isopropyl alcohol, IPA), the most important factors in the electron beam-induced fabrication process, is systematically controlled to find the conditions for the synthesis of the particle structure suitable for PEMFC applications. Furthermore, the effects of the structural changes on the electrochemical properties of the catalysts are thoroughly investigated. Through in-depth studies, it is clearly revealed that while dispersants control the nucleation step of monomers affecting the degree of dispersion of nanoparticles, radical scavengers with strong oxidizing power have an effect on the particle growth rate. Therefore, this study is expected to present the applicability of low-energy electron beam to the mass production of metal nanocatalysts for PEMFCs, and to provide insights into the fabrication of nanoparticles using low-energy electron beams.