Synthesis and Characterization of an Environmentally Friendly Phenol–Formaldehyde Resin Modified with Waste Plant Protein

Author:

Li Hanyin1,Wang Sen2,Zhang Xiang1,Wu Hao1,Wang Yujie1,Zhou Na1,Zhao Zijie1,Wang Chao12,Zhang Xiaofan13,Wang Xian2,Li Cheng1ORCID

Affiliation:

1. College of Forestry, Henan Agricultural University, Zhengzhou 450002, China

2. College of Landscape Architecture and Art, Henan Agricultural University, Zhengzhou 450002, China

3. Bureau of Agricultural and Rural Affairs, Luanchuan County, Luoyang 471500, China

Abstract

To develop a lower-cost, excellent-performance, and environmentally friendly phenol–formaldehyde (PF) resin, soybean meal was used to modify PF resin, and soybean meal–phenol–formaldehyde (SMPF) resins were prepared. This reveals the effect of soybean meal on the structural, bonding, and curing properties of PF resin, which are very important for its applications in the wood industry. The resins’ physicochemical properties and curing performance were investigated, showing that SMPF resins have higher curing temperatures than PF resin. The Fourier transform infrared spectroscopy results indicated that a cross-linking reaction occurred between the amino groups of soybean protein and the hydroxymethyl phenol. Moreover, with the addition of soybean meal, the viscosity of SMPF increased while the gel time decreased. It is worth mentioning that SMPF-2 resin has favorable viscosity, short gel time, low curing temperature (135.78 °C), and high water resistance and bonding strength (1.01 MPa). Finally, all the plywoods bonded with SMPF resins have good water resistance and bonding strength, which could meet the standard (GB/T 17657-2013, type I) for plywood. The optimized SMPF resins showed the potential for application to partially replace PF resin in the wood industry.

Funder

The Special Fund for Young Talents in Henan Agricultural University

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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