Stimuli Responsive Features of Organic RTP Materials: An Intriguing Carbazole‐Cyclic Triimidazole Derivative-Reference-Cited by-同舟云学术

Stimuli Responsive Features of Organic RTP Materials: An Intriguing Carbazole‐Cyclic Triimidazole Derivative

Published:2023-05-17 Issue:38 Volume:29 Page:
ISSN:0947-6539
Container-title:Chemistry – A European Journal
language:en
Short-container-title:Chemistry A European J

Author:

Malpicci Daniele¹²,Forni Alessandra²³^ORCID,Botta Chiara⁴,Giannini Clelia¹,Lucenti Elena²³,Marinotto Daniele²³,Maver Daniele¹²,Carlucci Lucia¹,Cariati Elena¹²³^ORCID

Affiliation:

1. Department of Chemistry Università degli Studi di Milano via Golgi 19 20133 Milano Italy

2. Institute of Chemical Sciences and Technologies “Giulio Natta” (SCITEC) of CNR via Golgi 19 20133 Milano Italy

3. INSTM Research Unit of Milano via Golgi 19 20133 Milano Italy

4. Institute of Chemical Sciences and Technologies “Giulio Natta” (SCITEC) of CNR via Corti 12 20133 Milano Italy

Abstract

AbstractStimuli responsive luminescent materials possessing room temperature phosphorescence (RTP) are extremely desirable for various applications. The here investigated derivative of cyclic triimidazole (TT) functionalized with carbazole (Cz), namely TT‐Ph‐Cz, belongs to this class. TT‐Ph‐Cz possesses high conformational freedom resulting in rigidochromic and multi‐stimuli responsive emissive behavior. It has been isolated as MeOH‐solvated and de‐solvated forms characterized by distinctive emissive features. In particular, the solvated form, in which hydrogen bonds with MeOH inhibit competitive non‐radiative deactivation channels, possesses a higher quantum yield associated with a strong phosphorescence contribution which is preserved in DMSO/water solutions.

Publisher

Wiley

Subject

General Chemistry,Catalysis,Organic Chemistry

Reference62 articles.

1. Room‐Temperature Phosphorescence Resonance Energy Transfer for Construction of Near‐Infrared Afterglow Imaging Agents

2. Ultrabright red AIEgens for two-photon vascular imaging with high resolution and deep penetration

3. Organic Room Temperature Phosphorescence Materials for Biomedical Applications

4. Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer

Cited by 4 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Multi Stimuli Responsive Dual Aggregation‐Induced Emission and Photochromic Behavior of a Tetraphenyl Substituted Triphenylamine Derivative and its Application as Anti‐counterfeiting Agent;Chemistry – A European Journal;2024-07-30

2. 3-Ethynyltriimidazo[1,2-a:1′,2′-c:1″,2″-e][1,3,5]triazine Dual Short- and Long-Lived Emissions with Crystallization-Enhanced Feature: Role of Hydrogen Bonds and π-π Interactions;Molecules;2024-04-25

3. A small D-A molecule with highly heat-resisting room temperature phosphorescence for white emission and anti-counterfeiting;Chinese Journal of Structural Chemistry;2024-03

4. ε-Polylysine organic ultra-long room-temperature phosphorescent materials based on phosphorescent molecule doping;Chemical Science;2024