Structured Cerium–Manganese Catalysts Supported on Nickel Foam for Toluene Oxidation by Electric Internal Heating

Abstract

AbstractStructured catalysts are widely used in catalytic oxidation of gaseous pollutants, hot catalysis is usually needed to assist the reaction in the catalytic process. Herein, a Ce‐modified manganese oxide octahedral molecular sieves (Ce‐OMS‐2) structured catalyst supported on foam nickel was prepared through impregnation process. A systematically quantitative testing on the toluene catalytic oxidation effectiveness of this structured catalyst was conducted through catalyst evaluation device, combining a series of characterization methods, such as XRD and SEM, the structure‐activity relationship was established. Assisted with electric internal heating and ozone oxidation environments, this structured catalyst exhibits excellent catalytic oxidation performance for oxidative decomposition of toluene even under high humidity conditions. The results showed that the ozone‐coupled structured nickel foam catalyst increased the decomposition efficiency of toluene from 25 % (without catalyst and heating) to 55 % (with catalyst and without heating) and the electric internal heating can significantly improve the reactivity and moisture resistance of the structured nickel‐foam catalyst, at 90 % RH and 40000 h−1, 50000 ppb O3 and 40 mg/m3 toluene was maintained 100 % catalytic efficiency. The high‐efficiency non‐precious metal‐based electrothermal catalyst prepared herein is expected to have certain enlightenment for the purification of VOCs.