The spontaneous hydrolysis of 2-pyridyl phosphate is a good model for the special mechanism for the hydrolysis of phosphate monoester monoanions
Author:
Affiliation:
1. Departamento de Química; Universidade Federal de Santa Catarina; Florianópolis SC 88040-900 Brazil
2. University Chemical Laboratory, Department of Chemistry; University of Cambridge; Cambridge CB2 1EW UK
Publisher
Wiley
Subject
Organic Chemistry,Physical and Theoretical Chemistry
Link
http://onlinelibrary.wiley.com/wol1/doi/10.1002/poc.3165/fullpdf
Reference9 articles.
1. Enzymatic Mechanisms of Phosphate and Sulfate Transfer
2. The Reactivity of Phosphate Esters. Monoester Hydrolysis
3. Biological Phosphoryl-Transfer Reactions: Understanding Mechanism and Catalysis
4. Activating Water: Important Effects of Non-leaving Groups on the Hydrolysis of Phosphate Triesters
5. Intramolecular General Base Catalysis in the Hydrolysis of a Phosphate Diester. Calculational Guidance to a Choice of Mechanism
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