Intramolecular General Base Catalysis in the Hydrolysis of a Phosphate Diester. Calculational Guidance to a Choice of Mechanism-Reference-Cited by-同舟云学术

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Intramolecular General Base Catalysis in the Hydrolysis of a Phosphate Diester. Calculational Guidance to a Choice of Mechanism

Published:2013-02-07 Issue:4 Volume:78 Page:1343-1353
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Kirby Anthony J.¹,Medeiros Michelle²,Mora José R.²,Oliveira Pedro S. M.²,Amer Almahdi³,Williams Nicholas H.³,Nome Faruk²

Affiliation:

1. University Chemical Laboratory, University of Cambridge, Cambridge CB2 1EW, U.K.

2. Departamento de Química, Universidade Federal de Santa Catarina, 88040-900 Florianópolis, SC, Brazil

3. Centre for Chemical Biology, Department of Chemistry, University of Sheffield, Sheffield S3 7HF, U.K.

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo302498g

Reference32 articles.

1. Activating Water: Efficient Intramolecular General Base Catalysis of the Hydrolysis of a Phosphate Triester

2. Functional Mimicry of Carboxypeptidase A by a Combination of Transition State Stabilization and a Defined Orientation of Catalytic Moieties in Molecularly Imprinted Polymers

3. 264. Ionization constants of heterocyclic substances. Part II. Hydroxy-derivatives of nitrogenous six-membered ring-compounds

4. Activating Water: Important Effects of Non-leaving Groups on the Hydrolysis of Phosphate Triesters

5. Hydrolysis of neutral phosphate and phosphonate esters catalysed by Co2+-chelates of tris-imidazolyl phosphines

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