Substrate‐Assisted, Transition‐Metal‐Free Diboration of Alkynamides with Mixed Diboron: Regio‐ and Stereoselective Access to trans ‐1,2‐Vinyldiboronates-Reference-Cited by-同舟云学术

Substrate‐Assisted, Transition‐Metal‐Free Diboration of Alkynamides with Mixed Diboron: Regio‐ and Stereoselective Access to trans ‐1,2‐Vinyldiboronates

Published:2017-03-29 Issue:18 Volume:56 Page:5111-5115
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew. Chem. Int. Ed.

Author:

Verma Astha¹,Snead Russell F.¹,Dai Yumin¹,Slebodnick Carla¹,Yang Yinuo²,Yu Haizhu²,Yao Fu³,Santos Webster L.¹^ORCID

Affiliation:

1. Department of Chemistry Virginia Tech 900 West Campus Drive Blacksburg VA 24061 USA

2. Department of Chemistry and Center for Atomic Engineering of Advanced Materials Anhui University Hefei Anhui 230601 P.R. China

3. Department of Chemistry and Materials Science University of Science and Technology of China Hefei Anhui 230026 P.R. China

Funder

Directorate for Mathematical and Physical Sciences

Publisher

Wiley

Subject

General Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.201700946

Reference77 articles.

2. Platinum(0)-catalyzed diboration of alkynes

3. Platinum(0)-Catalyzed Diboration of Alkynes with Tetrakis(alkoxo)diborons: An Efficient and Convenient Approach to cis-Bis(boryl)alkenes

4. Mechanistic Investigation of Stoichiometric Alkyne Insertion into Pt−B Bonds and Related Chemistry Bearing on the Catalytic Diborylation of Alkynes Mediated by Platinum(II) Diboryl Complexes

5. Synthesis and Characterization of Platinum(II)−Bis(boryl) Catalyst Precursors for Diboration of Alkynes and Diynes: Molecular Structures of cis-[(PPh3)2Pt(B-4-Butcat)2], cis-[(PPh3)2Pt(Bcat)2], cis-[(dppe)Pt(Bcat)2], cis-[(dppb)Pt(Bcat)2], (E)-(4-MeOC6H4)C(Bcat)CH(Bcat), (Z)-(C6H5)C(Bcat)C(C6H5)(Bcat), and (Z,Z)-(4-MeOC6H4)C(Bcat)C(Bcat)C(Bcat)C(4-MeOC6H4)(Bcat) (cat = 1,2-O2C6H4; dppe = Ph2PCH2CH2PPh2; dppb = Ph2P(CH2)4PPh2)

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