Affiliation:
1. State Key Laboratory of Phytochemistry and Plant Resources in West China Kunming Institute of Botany, University of Chinese Academy of Sciences, Chinese Academy of Sciences Kunming Yunnan 650201 China
Abstract
Comprehensive SummaryCollective syntheses of A. baumannii CPS K43, K47 and K88 repeating units have been accomplished via a new α‐glycosylation method with GlcN3 as donors, which features: 1) mild reaction conditions, 2) good to high yields, 3) excellent stereoselectivities. The synthetic route also highlights an orthogonal one‐pot coupling strategy on the basis of glycosyl ortho‐(1‐phenylvinyl)benzoates for stereoselective constructions of both 1,2‐trans and 1,2‐cis glycosidic bonds, precluding the issues of aglycone transfer.
Funder
National Natural Science Foundation of China
Cited by
3 articles.
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