Dual Modification of Chayotextle Starch: Effect on Physicochemical, Functional, and Structural Properties

Author:

Isaac Martínez‐Trejo Gerardo1,Miguel Anaya‐Esparza Luis2,Vargas‐Torres Apolonio1,Pablo Hernández‐Uribe Juan1,Omar Viñas‐Bravo3

Affiliation:

1. Universidad Autónoma del Estado de Hidalgo Instituto de Ciencias Agropecuarias Av. Universidad km 1, Rancho Universitario Tulancingo de Bravo Hidalgo 43600 México

2. División de Ciencias Agropecuarias e Ingenierías Centro Universitario de los Altos Universidad de Guadalajara Tepatitlán de Morelos Jalisco CP 47600 México

3. Instituto de Química Aplicada Universidad del Papaloapan, OAX, Circuito Central 200, Col. Parque Industrial Tuxtepec 68301 México

Abstract

AbstractChemically modified starches are widely used as food additives to improve the appearance and physicochemical and biological properties of foods. The aim of this work is to chemically modify chayotextle (Sechium edule) starch by hydroxypropylation‐crosslinking, and evaluate the effects of degree of substitution (DS), swelling power (SP), solubility index (SI), pasting, thermal properties, and morphological and molecular characteristics. Polar‐Tex (modified maize starch) is used as control. The modified chayotextle starches (CHSs) exhibit a white color and DS values between 0.34% and 1.19% hydroxypropyl, dependening on propylene oxide concentration‐response. In addition, the SP and pasting properties are higher in modified CHS than in native CHS and Polar‐Tex. The SI and temperature of gelatinization of modified starches decrease compared to native sample. The morphology of native and modified CHS granules is spherical and oval. Fourier transform infrared and nuclear magnetic resonance studies confirm the structural modifications of CHS by hydroxypropylation‐crosslinking. Dual‐modified CHS can be potentially used as an additive in the food industry.

Publisher

Wiley

Subject

Organic Chemistry,Food Science

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