Impact of Treatment with Superheated Steam on the Structural, Thermal, and Functional Characteristics of Quinoa Starch

Author:

Almeida Raphael Lucas Jacinto1ORCID,Santos Newton Carlos1,Ferreira Iêda Letícia de Souza1,Pedro Marcelo da Silva1,Morais Jessica Renaly Fernandes1,de Oliveira Adolfo Pinheiro2,Ribeiro Victor Herbert de Alcântara3,Silva Virgínia Mirtes de Alcântara4,de Lima Thalis Leandro Bezerra5,de Moraes Maria Suiane5,Silva Semirames do Nascimento6,Freire Vitória de Andrade7,Galdino Pablícia Oliveira8,Silva Rebeca de Almeida8

Affiliation:

1. Department of Chemical Engineering Federal University of Rio Grande do Norte Rio Grande do Norte Natal 59078‐970 Brazil

2. Department Nutrition Federal University of Piaui Terezina Piaui 64049‐550 Brazil

3. Engineering and Management of Natural Resources Department Federal University of Campina Grande Paraiba Campina Grande 58429‐900 Brazil

4. Food Engineering College Campinas State University Campinas São Paulo 13083‐970 Brazil

5. Department Agricultural Engineering Federal University of Campina Grande Paraiba Campina Grande 58429‐900 Brazil

6. Department of Agricultural Sciences Federal University of Campina Grande Paraiba Pombal 58840‐000 Brazil

7. Department of Chemical Engineering Federal University of Campina Grande Paraiba Campina Grande 58429‐900 Brazil

8. Department of Chemistry State University of Paraiba Paraiba Campina Grande 58429‐500 Brazil

Abstract

AbstractThe objective of the study is to evaluate the impact of treatment with superheated steam on the structural, thermal, and functional characteristics of quinoa starch. The superheated steam treatment is applied to the starch at 130 and 170 °C for 1 and 4 min, then dried at 50 °C and stored. Moisture adsorption isotherms are performed at 25 °C, and data are fitted to the Oswin, GAB, and Peleg models. Structural characterization is done using XRD and FTIR, thermal analysis using DSC, and functional characterization include water absorption capacity (WAC), oil absorption capacity (OAC), and syneresis. The QS170/4 treatment shows a reduction in crystallinity index of up to 48.24%, with the appearance of the amylose‐lipid complex, an increase in initial and final gelatinization temperatures, and a decrease in enthalpy of up to 39.53%. For modified starches, WAC and OAC increase by 9% and 7%, respectively, and syneresis decreases significantly by 17.4%. The results demonstrate the feasibility of modifying quinoa starch with superheated steam treatment, which, unlike other methods, has the advantage of altering the amylose and amylopectin chains in just a few minutes. Thus, the results show a new perspective for the use of superheated steam in starch modification.

Publisher

Wiley

Subject

Organic Chemistry,Food Science

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