Nickel‐Catalyzed Cross‐Electrophile Coupling of Aryl Phosphates with Aryl Bromides-Reference-Cited by-同舟云学术

Nickel‐Catalyzed Cross‐Electrophile Coupling of Aryl Phosphates with Aryl Bromides

Published:2023-07-17 Issue:15 Volume:365 Page:2511-2515
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Ren Jing‐Ao¹,Chen Xue¹,Gui Chao¹,Miao Chengping²,Chu Xue‐Qiang¹^ORCID,Xu Hao¹,Zhou Xiaocong¹²,Ma Mengtao³^ORCID,Shen Zhi‐Liang¹^ORCID

Affiliation:

1. Technical Institute of Fluorochemistry (TIF) Institute of Advanced Synthesis School of Chemistry and Molecular Engineering Nanjing Tech University Nanjing 211816 People's Republic of China

2. College of Biological, Chemical Science and Engineering Jiaxing University 118 Jiahang Road Jiaxing 314001 People's Republic of China

3. College of Science Nanjing Forestry University Nanjing 210037 People's Republic of China

Abstract

AbstractA step‐economical and operationally simple nickel‐catalyzed cross‐electrophile coupling of aryl phosphates with aryl bromides through C−O bond cleavage, which precluded the employment of relatively moisture‐labile and unreadily available organometallics, was developed. The reaction proceeded smoothly in the presence of magnesium turnings and lithium chloride in THF to afford the corresponding biaryls in moderate to good yields with reasonable functionality tolerance.

Funder

Nanjing Tech University

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

China Scholarship Council

Publisher

Wiley

Subject

General Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202300663

Reference84 articles.