Nickel‐Catalyzed Reductive Amidation of Aryl Sulfonium Salts with Isocyanates for Amide Synthesis via C−S Bond Activation-Reference-Cited by-同舟云学术

Nickel‐Catalyzed Reductive Amidation of Aryl Sulfonium Salts with Isocyanates for Amide Synthesis via C−S Bond Activation

Published:2024-09-12 Issue: Volume: Page:
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Chen Xue¹,Xu Meng‐Ke¹,Zhang Xuan‐Qi¹,Miao Chengping²,Chu Xue‐Qiang¹^ORCID,Rao Weidong³^ORCID,Xu Hao¹,Zhou Xiaocong¹²,Shen Zhi‐Liang¹^ORCID

Affiliation:

1. Technical Institute of Fluorochemistry (TIF) Institute of Advanced Synthesis School of Chemistry and Molecular Engineering Nanjing Tech University Nanjing 211816 People's Republic of China

2. College of Biological Chemical Science and Engineering Jiaxing University 118 Jiahang Road Jiaxing 314001 People's Republic of China

3. Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-Forest Biomass College of Chemical Engineering Nanjing Forestry University Nanjing 210037 People's Republic of China

Abstract

AbstractA nickel‐catalyzed reductive amidation of aryl sulfonium salts with isocyanates for amide synthesis via C−S bond cleavage was developed. The reactions proceeded smoothly at ambient temperature in the presence of nickel catalyst and manganese metal in DMF to give a variety of amides in moderate to good yields with wide functional group tolerance.

Funder

Nanjing Tech University

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202400424

Reference70 articles.

2. Rethinking amide bond synthesis

3. Nonclassical Routes for Amide Bond Formation

4. Metal-catalysed approaches to amide bond formation

5. Catalytic amide formation from non-activated carboxylic acids and amines

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